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Article – Journal of Advanced Chemical Sciences

Journal of Advanced Chemical Sciences, Volume 3,Issue 1,2017 Pages 445-448


Effect of Transitional Metal Ions on Photodegradation of Remazol Black B (RBB) in the Aqueous Suspension of ZnO under Solar Light Irradiation
Md. Obaidullah, M.J. Miah, Md.N. Kayes, Noboru Suzuki, Md.M. Hossain


This work is licensed under a Creative Commons Attribution 4.0 International License

The photocatalytic decolorizing of Remazol Black B (RBB) has been performed in the presence of ZnO suspension and the momentum of the reaction was eagle-eyed spectrophotometrically. The impact of various operating parameters such as amount of photocatalyst, the effect of addition of transition metal ions (Fe3+, Co2+, Pb2+ and Ni2+ ions from Fe(NO3)3.9H2O, Co(NO3)2.6H2O, Pb(NO3)2 and Ni(NO3)2.6H2O salt precursors, respectively), concentration variations of Co2+ and Fe3+ ions, has been enquired. It was observed that trace quantities of Co2+ and Fe3+ ions boost the reaction rate to some extent. The augmentation in the photocatalytic activity might be due to halt the recombination of electron-hole pairs by trapping photogenerated electrons because of incorporation of these metal ions on the semiconductor surface. On the other hand, the addition of Pb2+ and Ni2+ ions in aqueous medium impede photodegradation efficiency by blocking the active sites.



Keywords: Photocatalyst; Solar Light; Transition Metal; Remazol Black B;

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